different between ketol vs ketal

ketol

English

Etymology

Blend of ketone +? indol.

Noun

ketol (plural ketols)

  1. (organic chemistry) A hydroxyketone (e.g., an acyloin).
    • 1962, James A. Moore, Erich Heftmann, Chapter 2: Chemistry of the adrenocortical steroids, Helen Wendler Deane, The Adrenocortical Hormones, Part 1, Springer-Verlag, page 221,
      The 21-hydroxyl group in the ?-ketol side chain is very easily esterified, and in many of the synthetic routes leading to these side chains the ketol acetate is still formed.
    • 2010, Daniel L. Purich, Enzyme Kinetics: Catalysis and Control, Elsevier, Academic Press, page 201,
      Consider the enolization (Scheme 3.26) of the methyl ester of acetoacetic acid, a reaction involving ketol-enol tautomerism.
    • 2011, Erich Heftmann, Chromatography of Steroids, Elsevier, page 29,
      The steroid acetates are stable derivatives, having the desirable property that the electron-capture detector (ECD) selectively responds to acetyl derivatives of ?-ketols [958].

Derived terms

  • ketolic

Hyponyms

(hydroxyketone): ?-hydroxy ketone (acyloin), ?-hydroxy ketone (aldol)

Anagrams

  • Kotel

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ketal

English

Noun

ketal (plural ketals)

  1. (organic chemistry) Any acetal derived from a ketone

Derived terms

Anagrams

  • latke, talke

ketal From the web:

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